It was raining at the time of the crash but it's unclear if the weather was a factor.
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Police say one of the drivers tried to run from the scene. That person was caught.
Both drivers were taken to the hospital with non-life threatening injuries. One was arrested for trying to flee the scene and suspicion of driving under the influence.
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Both directions of Berryessa Road were blocked for about a half hour while police officers swept debris off the road.
Eastbound lanes remained closed at 6:45 a.m. but two lanes of westbound traffic are now open.